Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/95013
Title: Syntheses and structures of palladium(II) and platinum(II) complexes with tridentate (Ph2PCH2CH2CH2)2S and its arsenic analogue
Authors: Cheng, C.R.
Leung, P.-H. 
Mok, K.F. 
Keywords: Arsine
C-h-⋯o hydrogen bond
Palladium complexes
Phosphine
Platinum complexes
Six-membered chelate ring
Issue Date: 30-Jul-1997
Source: Cheng, C.R.,Leung, P.-H.,Mok, K.F. (1997-07-30). Syntheses and structures of palladium(II) and platinum(II) complexes with tridentate (Ph2PCH2CH2CH2)2S and its arsenic analogue. Inorganica Chimica Acta 260 (2) : 137-143. ScholarBank@NUS Repository.
Abstract: A series of square-planar complexes [MLCl]ClO4 (M=Pd(II), Pt(II); L=bis(3-(diphenylphosphino)propyl)sulfide (psp), bis(3-(diphenylarsino)propyl)sulfide (asa)) have been prepared and characterized. The X-ray crystal structures of two of them have been determined: [Pd(psp)Cl]ClO4, P21/c, a=12.519(2), b=15.766(2), c=16.501(2) Å, β= 105.22(1)°, Z=4; and [Pt(asa)Cl]ClO4, P2]/ c, a= 12.583 (5), b=16.007(6), c=16.549(6) Å, β= 104.89(3)°, Z=4. In both structures, there is a conformational disorder between the chair and skew-boat orientation in one of the two six-membered chelate rings. The C-H-⋯-O hydrogen bond between the hybrid ligand and the perchlorate counter ion that induces the conformational disorder is discussed.
Source Title: Inorganica Chimica Acta
URI: http://scholarbank.nus.edu.sg/handle/10635/95013
ISSN: 00201693
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

22
checked on Feb 17, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.