Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/95011
Title: Syntheses and properties of N-trifluoromethylgermaimine, CF3NGeH2, and N-bis (trifluoromethyl) nitroxy-germaimine, (CF3)2NON=GeH2
Authors: Ang, H.G. 
Lee, F.K.
Keywords: Bis (trifluoromethyl)nitroxy-germaimine
IR spectroscopy
Mass spectrometry
NMR spectroscopy
Syntheses
Trifluoromethylgermaimine
Issue Date: Dec-1995
Citation: Ang, H.G.,Lee, F.K. (1995-12). Syntheses and properties of N-trifluoromethylgermaimine, CF3NGeH2, and N-bis (trifluoromethyl) nitroxy-germaimine, (CF3)2NON=GeH2. Journal of Fluorine Chemistry 75 (2) : 181-186. ScholarBank@NUS Repository.
Abstract: The germaimines RN=GeH2 [where R=CF3 and (CF3)2NO], synthesised by methods involving condensation reactions of GeH4 with CF3NO and (CF3)2NONO respectively, underwent addition reactions with HI to give RNHGeH2I and stepwise substitution reactions with (CF3)2NO to afford the derivatives RN=GeH[ON(CF3)2]and RN=Ge[ON(CF3)2]2, together with a quantitative amount of (CF3)2NOH. These nitroxy derivatives have been found to undergo cleavage reactions with HCl to give the corresponding chloro derivatives, namely RN=GeCl[ON(CF3)2] and RN=GeCl2. © 1995.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95011
ISSN: 00221139
Appears in Collections:Staff Publications

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