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|Title:||Syntheses and characterization of some porphyrins and metalloporphyrins|
|Source:||Ji, L.N.,Liu, M.,Hsieh, A.K. (1990-12-03). Syntheses and characterization of some porphyrins and metalloporphyrins. Inorganica Chimica Acta 178 (1) : 59-65. ScholarBank@NUS Repository.|
|Abstract:||We have previously reported  that metalloporphyrins can be regarded as an active centre of cytochrome P-450 model enzyme systems. In this report, twelve derivatives of tetraphenyl porphyrins with electron- withdrawing and -donating substituents in the benzene ring, and their Fe(III) and Mn(III) complexes have been prepared, some of which have not been reported. The synthetic compounds were identified by element analysis, mass spectrometry and paramagnetic susceptibility. Their structures were confirmed by UV-Vis, IR and 1H NMR spectrometry. The spectral characteristics of the compounds are also discussed. © 1990.|
|Source Title:||Inorganica Chimica Acta|
|Appears in Collections:||Staff Publications|
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