Please use this identifier to cite or link to this item:
|Title:||Supramolecular Sn⋯Cl associations in diorganotin dichlorides and their influence on molecular geometry as studied by ab initio molecular orbital calculations|
|Source:||Buntine, M.A., Kosovel, F.J., Tiekink, E.R.T. (2003-09-01). Supramolecular Sn⋯Cl associations in diorganotin dichlorides and their influence on molecular geometry as studied by ab initio molecular orbital calculations. CrystEngComm 5 : 331-336. ScholarBank@NUS Repository. https://doi.org/10.1039/b308922c|
|Abstract:||A number of supramolecular architectures based on hypervalent Sn⋯Cl interactions are observed in a series of eight R2SnCl2 structures ranging from tetrameric assemblies to a variety of polymeric motifs. The absence of Sn⋯Cl interactions in the crystal lattice of tBu 2SnCl2 may be attributed to the bulky size of the tin-bound t-butyl groups that precludes such interactions. The influence of the supramolecular aggregation upon molecular geometry has been investigated using ab initio molecular orbital calculations. These show that invariably more symmetric structures are observed in the absence of hypervalent Sn⋯Cl interactions. © The Royal Society of Chemistry 2003.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 14, 2018
WEB OF SCIENCETM
checked on Jan 22, 2018
checked on Feb 19, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.