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|Title:||Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S) 2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)|
Andy Hor, T.S.
|Citation:||Bridson, J.H., Henderson, W., Nicholson, B.K., Andy Hor, T.S. (2006-01-20). Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S) 2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II). Inorganica Chimica Acta 359 (2) : 680-684. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2005.06.082|
|Abstract:||Reaction of [Pt2(μ-S)2(PPh3) 4] with a range of zinc(II) and cobalt(II) complexes ML2, where L is a β-diketonate ligand CH3COCHCOCH3, PhCOCHCOPh, CF3COCHCOTh (Th = 2-thienyl)] permits the synthesis of adducts [Pt2(μ-S)2(PPh3) 4M(diketonate)]+, isolated as their BPh4- salts in moderate yields. The cobalt and zinc acetylacetonate complexes were characterised by single-crystal X-ray diffraction studies, which reveal isomorphous structures, with tetrahedral heterometal centres. © 2005 Elsevier B.V. All rights reserved.|
|Source Title:||Inorganica Chimica Acta|
|Appears in Collections:||Staff Publications|
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