Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2006.01.028
Title: Substitution derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13: Monosubstituted group 15 derivatives
Authors: Pereira, L.J.
Leong, W.K. 
Keywords: Heterometallic complexes
Osmium
Phosphanes
Ruthenium
Issue Date: 15-May-2006
Citation: Pereira, L.J., Leong, W.K. (2006-05-15). Substitution derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13: Monosubstituted group 15 derivatives. Journal of Organometallic Chemistry 691 (11) : 2448-2456. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2006.01.028
Abstract: Tertiary group 15 ligand monosubstituted derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13 have been prepared and their solid state and solution structures examined. A number of isomeric structural types have been identified in solution, and these appear to be correlated to disorder in the solid state. Hydride fluxionality and restricted rotation about the metal-phosphorus bond have also been observed. © 2006 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94963
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2006.01.028
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