Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.poly.2006.02.012
Title: Substitution derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13: Disubstituted group 15 derivatives
Authors: Pereira, L.J.
Leong, W.K. 
Keywords: Chemical exchange
Heterometallic complexes
Osmium
Phosphanes
Ruthenium
Issue Date: 21-Aug-2006
Source: Pereira, L.J., Leong, W.K. (2006-08-21). Substitution derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13: Disubstituted group 15 derivatives. Polyhedron 25 (12) : 2392-2400. ScholarBank@NUS Repository. https://doi.org/10.1016/j.poly.2006.02.012
Abstract: The structures in the solid state and solution state of tertiary group 15 ligand disubstituted derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13 are examined. Four structural types have been characterised crystallographically, including one in which both phosphine ligands were substituted at the unique ruthenium vertex. In solution, there are many more isomers present, most of which are rapidly interconverting via hydride migrations. Substitution appears to be directed electronically to the ruthenium vertex, although steric hindrance appears to drive subsequent isomerisation via migration of the second group 15 ligand. © 2006 Elsevier Ltd. All rights reserved.
Source Title: Polyhedron
URI: http://scholarbank.nus.edu.sg/handle/10635/94962
ISSN: 02775387
DOI: 10.1016/j.poly.2006.02.012
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

5
checked on Mar 7, 2018

WEB OF SCIENCETM
Citations

5
checked on Mar 7, 2018

Page view(s)

21
checked on Feb 25, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.