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|Title:||Substituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene|
|Authors:||Hor, T.S.A. |
|Source:||Hor, T.S.A.,Phang, L.-T. (1990). Substituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene. Polyhedron 9 (18) : 2305-2308. ScholarBank@NUS Repository.|
|Abstract:||A series of polynuclear heterometallic complexes (OC)5M(μ-dppf)M′(CO)5 (M, M′ = Cr, Mo, W; M ≠ M′) and (OC)5M(μ-dppf)Mn2(CO)9 (dppf = 1,1′-bis(diphenylphosphino) ferrocene) has been synthesized at room temperature based on the metallo-ligand M(CO)5(η1-dppf). The use of amine oxide as a decarbonylant preserves the integrity of the MnMn bond. The mixed metals are linked by a singly-bridging diphosphine group which does not perturb the two metal spheres. © 1990.|
|Appears in Collections:||Staff Publications|
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