Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94948
Title: Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses
Authors: Hor, T.S.A. 
Issue Date: 13-Jan-1987
Citation: Hor, T.S.A. (1987-01-13). Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses. Journal of Organometallic Chemistry 319 (2) : 213-217. ScholarBank@NUS Repository.
Abstract: Trimethylamine N-oxide (TMNO)-initiated decarbonylations of Mo(CO)6 followed by phosphine additions yield the complexes Mo(CO)5(Ph2PCH2PPh2), which consists of a unidentate diphosphine, and the dinuclear phosphine-bridged complexes Mo2(CO)10(μ-Ph2P(CH2)nPPh2) (where n = 2, 3) at ambient temperatures. The IR and NMR (1H and 31P) spectroscopic and structural properties of these complexes are presented and discussed. Some thermal analytical data are summarised. © 1987.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94948
ISSN: 0022328X
Appears in Collections:Staff Publications

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