Please use this identifier to cite or link to this item: https://doi.org/10.1002/app.23541
Title: Studies on urethane-allophanate networks based on hydroxyl-terminated polybutadiene: Modeling of network parameters and correlation to mechanical properties
Authors: Sekkar, V.
Narayanaswamy, K.
Scariah, K.J.
Nair, P.R.
Sastri, K.S.
Ang, H.G. 
Keywords: 4,4′-di(isocyanatocyclohexyl)methane
Allophanate
Hydroxyl-terminated polybutadiene
Isophorone-di- isocyanate
Modeling
Network parameters
Polyurethane
Toluenedi-isocyanate
Issue Date: 5-Sep-2006
Source: Sekkar, V., Narayanaswamy, K., Scariah, K.J., Nair, P.R., Sastri, K.S., Ang, H.G. (2006-09-05). Studies on urethane-allophanate networks based on hydroxyl-terminated polybutadiene: Modeling of network parameters and correlation to mechanical properties. Journal of Applied Polymer Science 101 (5) : 2986-2994. ScholarBank@NUS Repository. https://doi.org/10.1002/app.23541
Abstract: Hydroxyl-terminated polybutadiene (HTPB)-based allophanate-urethane networks were prepared by reacting HTPB with di-isocyanates, such as toluene-di-isocyanate (TDI), isophorone-di-isocyanate (IPDI), and 4,4′-di(socyanatocyclohexyl)methane (H12MDI) at stoichiometric ratios (r-values) ranging from 1.0 to 1.5. The networks were characterized for mechanical and swell properties. The network parameters, such as "X," which is the fraction of urethane groups involved in the allophanate formation, and effective chain length (Lx) were calculated from experimen-tal crosslink density values determined from swell data, using a-model equations developed by Marsh. Excellent linear correlations were obtained between mechanical properties and the calculated network parameters. © 2006 Wiley Periodicals, Inc.
Source Title: Journal of Applied Polymer Science
URI: http://scholarbank.nus.edu.sg/handle/10635/94930
ISSN: 00218995
DOI: 10.1002/app.23541
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