Please use this identifier to cite or link to this item: https://doi.org/10.1021/om050200p
Title: Square planar versus tetrahedral NiS 4 cores in the coordination spheres of (HMB)Ru(II) and Cp*Ru(III) and a related CuS 4 complex. Synthetic, single-crystal X-ray diffraction, and magnetic studies {HMB = η 6-C 6Me 6 and Cp* = η 5-C 5Me 5}
Authors: Shin, R.Y.C.
Teo, M.E.
Tan, G.K.
Koh, L.L. 
Vittal, J.J. 
Goh, L.Y. 
Murray, K.S.
Moubaraki, B.
Zhou, X.-Y.
Issue Date: 15-Aug-2005
Source: Shin, R.Y.C., Teo, M.E., Tan, G.K., Koh, L.L., Vittal, J.J., Goh, L.Y., Murray, K.S., Moubaraki, B., Zhou, X.-Y. (2005-08-15). Square planar versus tetrahedral NiS 4 cores in the coordination spheres of (HMB)Ru(II) and Cp*Ru(III) and a related CuS 4 complex. Synthetic, single-crystal X-ray diffraction, and magnetic studies {HMB = η 6-C 6Me 6 and Cp* = η 5-C 5Me 5}. Organometallics 24 (17) : 4265-4273. ScholarBank@NUS Repository. https://doi.org/10.1021/om050200p
Abstract: Square planar cores in comparison to tetrahedral NiS 4 cores, in the coordination spheres of (HMB)Ru(II) and Cp*Ru(III) and a related CuS 4 complex were investigated. The reactions were carried out using conventional Schelenk techiques under argon in a M.Braun labmaster 130 inert gas system. Magnetic susceptibility measurements were made on ≅20mg samples of powders contained in a gel capsule which was held in the center of a soda straw. The results show that magnetic studies of the neat solids yield information compatible with the spectral, crystallographic, and electron count /M-M bonded data, as well as with spin-coupling trinuclear models.
Source Title: Organometallics
URI: http://scholarbank.nus.edu.sg/handle/10635/94863
ISSN: 02767333
DOI: 10.1021/om050200p
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