Please use this identifier to cite or link to this item:
|Title:||Silver(I) macrocycles and coordination polymers containing pyridyl carboxylate and phosphine ligands|
|Keywords:||[2+2] cycloaddition reactions|
|Source:||Kole, G.K., Chin, C.K., Tan, G.K., Vittal, J.J. (2013-03-22). Silver(I) macrocycles and coordination polymers containing pyridyl carboxylate and phosphine ligands. Polyhedron 52 : 1440-1448. ScholarBank@NUS Repository. https://doi.org/10.1016/j.poly.2012.04.003|
|Abstract:||Six Ag(I) coordination compounds containing pyridyl carboxylates [namely of trans-3-(3′-pyridyl) acrylic acid (3-PAH), trans-3-(4′-pyridyl) acrylic acid (4-PAH), and 4-trans-2-(pyrid-4-yl-vynyl) benzoic acid (Hpvba)] and phosphine ligands [namely triphenylphosphine, 1,1-bis-(diphenylphosphino) methane (dppm), 1,2-bis-(diphenylphosphino) ethane (dppe) and 1,3-bis-(diphenylphosphino) propane (dppp)] are described. By varying the combination of silver salts and bridging ligands, we have synthesized 0D, 1D, 2D and 3D architectures of silver(I) coordination compounds and polymers. The coordination environments and geometries around Ag(I) are highly dependent on the coordination mode of carboxylate 'O' (whether monodentate, μ1,1 or μ1,3). On the other hand, the dimensionality of the coordination polymers depends on the bridging diphosphine ligands and shape of the pyridyl carboxylates.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 14, 2018
WEB OF SCIENCETM
checked on Jan 22, 2018
checked on Feb 19, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.