Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2005.06.078
Title: Silver decoration of a palladacycle through "spacer-guest" interaction
Authors: Teo, P.
Koh, L.L. 
Hor, T.S.A. 
Keywords: Heterometallic
Host-guest interaction
Macrocycle
Palladium
Silver
Spacer-guest
Issue Date: 1-Aug-2006
Citation: Teo, P., Koh, L.L., Hor, T.S.A. (2006-08-01). Silver decoration of a palladacycle through "spacer-guest" interaction. Inorganica Chimica Acta 359 (11) : 3435-3439. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2005.06.078
Abstract: [Pd(dppf)(MeCN)2](OTf)2 [dppf = 1,1′-bis(diphenylphosphino)ferrocene, OTf = triflate] reacts with pyridyl acetic acid (PyAcOH) to yield a dipalladium ring structure, [Pd2(dppf)2(μ-PyOAc)2](OTf)2 (1). The doubly-bridging ligands exhibit basicity at the pendant carboxyl oxygen to attract AgX (X = OTf or CF3CO2) to form [Pd2Ag2(dppf)2(PyOAc)2(OTf)4] (2) and [Pd2Ag2(dppf)2(PyOAc)2(OTf)2(CF3CO2)2] (3), respectively. Complexes 1 and 2 have been crystallographically characterized. Similar spacer-guest affinity is not found in the Pt(II) or isonicotinate analogues. © 2005 Elsevier B.V. All rights reserved.
Source Title: Inorganica Chimica Acta
URI: http://scholarbank.nus.edu.sg/handle/10635/94805
ISSN: 00201693
DOI: 10.1016/j.ica.2005.06.078
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

14
checked on Sep 17, 2018

WEB OF SCIENCETM
Citations

13
checked on Sep 5, 2018

Page view(s)

25
checked on Jul 20, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.