Please use this identifier to cite or link to this item: https://doi.org/10.1039/b812644e
Title: Self-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine)
Authors: Li, J.
Hor, T.S.A. 
Issue Date: 2008
Source: Li, J., Hor, T.S.A. (2008). Self-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine). Dalton Transactions (46) : 6619-6623. ScholarBank@NUS Repository. https://doi.org/10.1039/b812644e
Abstract: The high reactivity of Group 10 metal-metal bonded complexes towards platinum chalcogenide compounds have been demonstrated through the successful isolation of a number of novel homo- and hetero-polynuclear complexes. A d 8-d9 pentanuclear sulfide cluster with a Pd3 triangle sandwiched by two Pt2 sheaths with peripheral protection from coordinated and pendant pyridyls has been isolated and characterized. Other related aggregates with the {Pt2M2X2} (X = S, Se) core have also been obtained from the addition of the [Pt2S 2] metalloligand to dinuclear Pd(I). © 2008 The Royal Society of Chemistry.
Source Title: Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/94788
ISSN: 14779226
DOI: 10.1039/b812644e
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