Please use this identifier to cite or link to this item: https://doi.org/10.1007/s10876-007-0138-5
Title: Reduced overlap population analysis for triosmium clusters
Authors: Morrison, E.C.
Leong, W.K. 
Tan, J.
Keywords: Alkoxy
Cluster
EHMO
Osmium
ROP
Issue Date: Sep-2007
Source: Morrison, E.C., Leong, W.K., Tan, J. (2007-09). Reduced overlap population analysis for triosmium clusters. Journal of Cluster Science 18 (3) : 753-763. ScholarBank@NUS Repository. https://doi.org/10.1007/s10876-007-0138-5
Abstract: The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal-metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os 3(μ-OEt)2(CO)10, 1b, and some of its group 15 derivatives Os3(μ-OEt)2(CO)9(EPh 3), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies. © 2007 Springer Science+Business Media, LLC.
Source Title: Journal of Cluster Science
URI: http://scholarbank.nus.edu.sg/handle/10635/94700
ISSN: 10407278
DOI: 10.1007/s10876-007-0138-5
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