Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94687
Title: Reactions of Trifluoronitrosomethane with bistrifluoromethylphosphorus compounds, (CF3)2PX (where x = H, Cl, CF3)
Authors: Ang, H.G. 
So, K.K.
Issue Date: Apr-1985
Source: Ang, H.G.,So, K.K. (1985-04). Reactions of Trifluoronitrosomethane with bistrifluoromethylphosphorus compounds, (CF3)2PX (where x = H, Cl, CF3). Journal of Fluorine Chemistry 27 (4) : 451-460. ScholarBank@NUS Repository.
Abstract: Trifluoronitrosomethane reacts with bis(trifluoromethyl)phosphine to give (CF3)2P(O)N(OH)CF3 and a small amount of (CF3)2NOH. On the other hand, the reactions with tris(trifluoromethyl)phosphine and bis(trifluoromethyl)chlorophosphine afford (CF3)2NOP(O)CF3N(CF3)2 and (CF3)2NP(O)(CF3)Cl respectively. Isomerisation of {A figure is presented} may be involved as found for the isomerisation of the phosphine, (CF3)2NOP(CF3)2, to the phosphoryl compound, (CF3)2NP(O)(CF3)2. Mechanisms for the above reactions are discussed. © 1985.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94687
ISSN: 00221139
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

38
checked on Feb 24, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.