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https://scholarbank.nus.edu.sg/handle/10635/94680
DC Field | Value | |
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dc.title | Reactions of spiked and open chain cluster hydrides with Au complexes: Skeletal rearrangement and crystal structures of heterometallic clusters [Au2Ru4(CO)12(μ4-PCF 3)(PMe3)2] and [Au2Ru4(CO)12(μ3-PCF 3)2(PPh3)2] | |
dc.contributor.author | Ang, H.-G. | |
dc.contributor.author | Ang, S.-G. | |
dc.contributor.author | Du, S. | |
dc.date.accessioned | 2014-10-16T08:38:51Z | |
dc.date.available | 2014-10-16T08:38:51Z | |
dc.date.issued | 1999-11-05 | |
dc.identifier.citation | Ang, H.-G.,Ang, S.-G.,Du, S. (1999-11-05). Reactions of spiked and open chain cluster hydrides with Au complexes: Skeletal rearrangement and crystal structures of heterometallic clusters [Au2Ru4(CO)12(μ4-PCF 3)(PMe3)2] and [Au2Ru4(CO)12(μ3-PCF 3)2(PPh3)2]. Journal of Organometallic Chemistry 589 (2) : 133-137. ScholarBank@NUS Repository. | |
dc.identifier.issn | 0022328X | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94680 | |
dc.description.abstract | Treatment of the spiked cluster [Ru4(CO)13(μ-H)2(μ4-PCF 3)] with [Au(PMe3)Cl] in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) results in deprotonation and metal core rearrangement from spiked to butterfly, yielding the heterometallic cluster [Au2Ru4(CO)12(μ4-PCF 3)(PMe3)2] 1. Reaction of the open chain cluster [Ru4(CO)12(μ-H)2(μ3-PCF 3)2] with [Au(PPh3)Cl] under similar conditions gives [Au2Ru4(CO)12(μ3-PCF 3)2(PPh3)2] 2 where the hydrides are simply replaced by AuPPh3 fragments. Clusters 1 and 2 are characterised by spectroscopy and X-ray crystallography. © 1999 Elsevier Science S.A. | |
dc.source | Scopus | |
dc.subject | Heterometallic cluster | |
dc.subject | Molecular structure | |
dc.subject | Open Chain | |
dc.subject | Ruthenium | |
dc.subject | Spiked | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Journal of Organometallic Chemistry | |
dc.description.volume | 589 | |
dc.description.issue | 2 | |
dc.description.page | 133-137 | |
dc.description.coden | JORCA | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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