Please use this identifier to cite or link to this item:
|Title:||Reactions of bis(trifluoromethyl)nitroxyl with CF3PX2 (where X = F, Cl, Br, I and CN) and P(CN)3|
|Authors:||Ang, H.G. |
|Citation:||Ang, H.G.,So, K.K. (1982-10). Reactions of bis(trifluoromethyl)nitroxyl with CF3PX2 (where X = F, Cl, Br, I and CN) and P(CN)3. Journal of Fluorine Chemistry 21 (2) : 221-242. ScholarBank@NUS Repository.|
|Abstract:||The reactions between bis(trifluoromethyl)nitroxyl and CF3PX2 (where X = F, Cl, Br and CN) in 2:1 molar ratio give addition products, [(CF3)2NO]2P(CF3)X2 . The bromo and cyano products are unstable. The former decomposes at room temperature to give bromine and perfluoro-2-azapropene, and the latter yields predominantly (CF3)2NOCF3. With CF3PI2, iodine displacement occurs to afford [(CF3)2NO]2PCF3. On the other hand, P(CN)3 affords [(CF3)2NO]3PO, (CF3)2NON(CF3)2 and paracyanogen. Mechanisms for these reactions are proposed. © 1982.|
|Source Title:||Journal of Fluorine Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Nov 2, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.