Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94674
Title: Reactions of bis(trifluoromethyl)nitroxyl with CF3PX2 (where X = F, Cl, Br, I and CN) and P(CN)3
Authors: Ang, H.G. 
So, K.K.
Issue Date: Oct-1982
Citation: Ang, H.G.,So, K.K. (1982-10). Reactions of bis(trifluoromethyl)nitroxyl with CF3PX2 (where X = F, Cl, Br, I and CN) and P(CN)3. Journal of Fluorine Chemistry 21 (2) : 221-242. ScholarBank@NUS Repository.
Abstract: The reactions between bis(trifluoromethyl)nitroxyl and CF3PX2 (where X = F, Cl, Br and CN) in 2:1 molar ratio give addition products, [(CF3)2NO]2P(CF3)X2 . The bromo and cyano products are unstable. The former decomposes at room temperature to give bromine and perfluoro-2-azapropene, and the latter yields predominantly (CF3)2NOCF3. With CF3PI2, iodine displacement occurs to afford [(CF3)2NO]2PCF3. On the other hand, P(CN)3 affords [(CF3)2NO]3PO, (CF3)2NON(CF3)2 and paracyanogen. Mechanisms for these reactions are proposed. © 1982.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94674
ISSN: 00221139
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

36
checked on Nov 2, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.