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https://doi.org/10.1016/j.jorganchem.2005.12.006
| Title: | Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes: An unusual case of amine activation | Authors: | Srinivasan, P. Tan, J. Leong, W.K. |
Keywords: | Alkynes Amine Heterometallic complexes Iridium Osmium |
Issue Date: | 1-Mar-2006 | Citation: | Srinivasan, P., Tan, J., Leong, W.K. (2006-03-01). Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes: An unusual case of amine activation. Journal of Organometallic Chemistry 691 (6) : 1288-1294. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.12.006 | Abstract: | Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes is activated by excess amine to afford the butterfly clusters Cp*IrOs3(CO)9(RCCR′); hinge-apex isomers are formed. In the case of PhCCH, another cluster Cp*IrOs3(CO)9(CCHPh)2, which contained two alkenyl moieties was also isolated. © 2005 Elsevier B.V. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94665 | ISSN: | 0022328X | DOI: | 10.1016/j.jorganchem.2005.12.006 |
| Appears in Collections: | Staff Publications |
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