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|Title:||Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes: An unusual case of amine activation|
|Citation:||Srinivasan, P., Tan, J., Leong, W.K. (2006-03-01). Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes: An unusual case of amine activation. Journal of Organometallic Chemistry 691 (6) : 1288-1294. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.12.006|
|Abstract:||Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes is activated by excess amine to afford the butterfly clusters Cp*IrOs3(CO)9(RCCR′); hinge-apex isomers are formed. In the case of PhCCH, another cluster Cp*IrOs3(CO)9(CCHPh)2, which contained two alkenyl moieties was also isolated. © 2005 Elsevier B.V. All rights reserved.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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