Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2005.12.006
Title: Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes: An unusual case of amine activation
Authors: Srinivasan, P.
Tan, J.
Leong, W.K. 
Keywords: Alkynes
Amine
Heterometallic complexes
Iridium
Osmium
Issue Date: 1-Mar-2006
Citation: Srinivasan, P., Tan, J., Leong, W.K. (2006-03-01). Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes: An unusual case of amine activation. Journal of Organometallic Chemistry 691 (6) : 1288-1294. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.12.006
Abstract: Reaction of the heteronuclear cluster Cp*IrOs3(μ-H) 4(CO)9 with alkynes is activated by excess amine to afford the butterfly clusters Cp*IrOs3(CO)9(RCCR′); hinge-apex isomers are formed. In the case of PhCCH, another cluster Cp*IrOs3(CO)9(CCHPh)2, which contained two alkenyl moieties was also isolated. © 2005 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94665
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2005.12.006
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

6
checked on Aug 8, 2018

WEB OF SCIENCETM
Citations

6
checked on Aug 8, 2018

Page view(s)

40
checked on Aug 3, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.