Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94661
Title: Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of...
Authors: Ang, H.G. 
Kwik, W.L. 
Ong, K.K.
Issue Date: Jan-1993
Source: Ang, H.G.,Kwik, W.L.,Ong, K.K. (1993-01). Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of.... Journal of Fluorine Chemistry 60 (1) : 43-48. ScholarBank@NUS Repository.
Abstract: Title full: Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of [Os3(CO)11(μ-ONC6F5)], [Os3(CO)9(μ3-NC6F5 )2], [Os3(CO)11(CH3 CN)] and Os3(CO)12. Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] in THF at room temperature yields a new triosmium cluster, [Os3(CO)11(μ-ONC6F5)] (I), where the pentafluorophenylnitroso ligand has been shown by X-ray crystallography to adopt an unusual bonding mode, with its nitrogen bridging two non-bonded osmium atoms and the oxygen atom bonded to one of the osmium atoms. The separation of [Os3(CO)11(μ-ONC6F5)] (I), [Os3(CO)9(μ3-NC6F 5)2] (II) and their parent triosmium clusters, i.e. [Os3(CO)11-(CH3CN)] and Os3(CO)12, by high-performance liquid chromatography is also described. © 1993.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94661
ISSN: 00221139
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