Please use this identifier to cite or link to this item: https://doi.org/10.1016/0022-1139(95)03354-8
Title: Preparation and properties of CF3As[ON(H)CF3]2 and (CF3)2AsON(H)CF3
Authors: Ang, H.G. 
Koh, C.H.
Keywords: Bis(trifluoromethyl)arsine
IR spectroscopy
Reactions
Thermal decomposition
Trifluoromethylarsine
Trifluoronitrosomethane
Issue Date: Jan-1996
Citation: Ang, H.G., Koh, C.H. (1996-01). Preparation and properties of CF3As[ON(H)CF3]2 and (CF3)2AsON(H)CF3. Journal of Fluorine Chemistry 76 (1) : 111-115. ScholarBank@NUS Repository. https://doi.org/10.1016/0022-1139(95)03354-8
Abstract: Trifluoronitrosomethane reacts with trifluoromethylarsine and bis(trifluoromethyl)arsine to afford CF3As[OBN(H)CF3]2 (A) and (CF3)2AsON(H)CF3 (B), respectively. Compound B has been found to decompose at 60 °C to give (CF3)2As(O)H, (CF3)2AsOH and (CF3)2AsF. The reactions of both A and B with anhydrous hydrogen chloride result in the cleavage of the As-O bond to afford quantitative yields of the respective arsenic chloride. Reactions of B with bis(trifluoromethyl)nitroxyl gives (CF3)2AsON(CF3)2, (CF3)2NOH, (CF3)2NH, CF3NO2, CF3NO and a non-volatile white solid.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94599
ISSN: 00221139
DOI: 10.1016/0022-1139(95)03354-8
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