Please use this identifier to cite or link to this item:
|Title:||Preparation and properties of CF3As[ON(H)CF3]2 and (CF3)2AsON(H)CF3|
|Authors:||Ang, H.G. |
|Source:||Ang, H.G., Koh, C.H. (1996-01). Preparation and properties of CF3As[ON(H)CF3]2 and (CF3)2AsON(H)CF3. Journal of Fluorine Chemistry 76 (1) : 111-115. ScholarBank@NUS Repository. https://doi.org/10.1016/0022-1139(95)03354-8|
|Abstract:||Trifluoronitrosomethane reacts with trifluoromethylarsine and bis(trifluoromethyl)arsine to afford CF3As[OBN(H)CF3]2 (A) and (CF3)2AsON(H)CF3 (B), respectively. Compound B has been found to decompose at 60 °C to give (CF3)2As(O)H, (CF3)2AsOH and (CF3)2AsF. The reactions of both A and B with anhydrous hydrogen chloride result in the cleavage of the As-O bond to afford quantitative yields of the respective arsenic chloride. Reactions of B with bis(trifluoromethyl)nitroxyl gives (CF3)2AsON(CF3)2, (CF3)2NOH, (CF3)2NH, CF3NO2, CF3NO and a non-volatile white solid.|
|Source Title:||Journal of Fluorine Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 14, 2018
checked on Feb 18, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.