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|Title:||Preparation and properties of CF3As[ON(H)CF3]2 and (CF3)2AsON(H)CF3|
|Authors:||Ang, H.G. |
|Citation:||Ang, H.G., Koh, C.H. (1996-01). Preparation and properties of CF3As[ON(H)CF3]2 and (CF3)2AsON(H)CF3. Journal of Fluorine Chemistry 76 (1) : 111-115. ScholarBank@NUS Repository. https://doi.org/10.1016/0022-1139(95)03354-8|
|Abstract:||Trifluoronitrosomethane reacts with trifluoromethylarsine and bis(trifluoromethyl)arsine to afford CF3As[OBN(H)CF3]2 (A) and (CF3)2AsON(H)CF3 (B), respectively. Compound B has been found to decompose at 60 °C to give (CF3)2As(O)H, (CF3)2AsOH and (CF3)2AsF. The reactions of both A and B with anhydrous hydrogen chloride result in the cleavage of the As-O bond to afford quantitative yields of the respective arsenic chloride. Reactions of B with bis(trifluoromethyl)nitroxyl gives (CF3)2AsON(CF3)2, (CF3)2NOH, (CF3)2NH, CF3NO2, CF3NO and a non-volatile white solid.|
|Source Title:||Journal of Fluorine Chemistry|
|Appears in Collections:||Staff Publications|
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