Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.saa.2005.02.050
Title: Photoelectron spectroscopy of free radicals: 4-Methyl-sulfonyloxy-TEMPO
Authors: Novak, I. 
Kovač, B.
Keywords: Free radicals
UV photoelectron spectroscopy
Issue Date: Dec-2005
Source: Novak, I., Kovač, B. (2005-12). Photoelectron spectroscopy of free radicals: 4-Methyl-sulfonyloxy-TEMPO. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 62 (4-5) : 915-917. ScholarBank@NUS Repository. https://doi.org/10.1016/j.saa.2005.02.050
Abstract: HeI and HeII photoelectron spectra of persistent free radical: 2,2,6,6-tetramethyl-4-(methylsulfonyloxy)piperidinyl-1-oxide (CH 3SO3-TEMPO) have been measured. The analysis of the electronic structure is based on comparison with the spectra of related radicals and with DFT calculations. The electronic structure of the nitroxide group in the title radical seems unaffected by the presence of substituent group. This is consistent with results observed for other nitroxide radicals and with the electrochemical oxidation potentials. © 2005 Elsevier B.V. All rights reserved.
Source Title: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
URI: http://scholarbank.nus.edu.sg/handle/10635/94521
ISSN: 13861425
DOI: 10.1016/j.saa.2005.02.050
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

4
checked on Feb 14, 2018

WEB OF SCIENCETM
Citations

3
checked on Jan 16, 2018

Page view(s)

22
checked on Feb 18, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.