Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.saa.2007.03.012
Title: Photoelectron spectroscopy and substituent effects in halonaphthalenes
Authors: Novak, I.
Harrison, L.J. 
Li, W.
Keywords: Photoelectron spectroscopy
Substituent effects
Issue Date: Jan-2008
Citation: Novak, I., Harrison, L.J., Li, W. (2008-01). Photoelectron spectroscopy and substituent effects in halonaphthalenes. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 69 (1) : 78-81. ScholarBank@NUS Repository. https://doi.org/10.1016/j.saa.2007.03.012
Abstract: The electronic structure of two isomeric dibromonaphthalenes (C10H6Br2) has been investigated by HeI/HeII photoelectron spectroscopy. The spectra were assigned by Green's functions calculations and comparison with the spectra of related dibromobenzenes (C6H4Br2). The analysis of π-orbital and halogen lone pair ionization energies, enabled us to determine the magnitude of bromine-bromine intramolecular interactions and distinguish between through-bond and through-space type interactions. We also discuss the halogen-halogen interactions in other polynuclear aromatics. © 2007 Elsevier B.V. All rights reserved.
Source Title: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
URI: http://scholarbank.nus.edu.sg/handle/10635/94520
ISSN: 13861425
DOI: 10.1016/j.saa.2007.03.012
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