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|Title:||Phase transition accompanied by transformation of an elusive discrete cyclic water heptamer to a bicyclic (H2O)7 cluster|
|Citation:||Mir, M.H., Vittal, J.J. (2007). Phase transition accompanied by transformation of an elusive discrete cyclic water heptamer to a bicyclic (H2O)7 cluster. Angewandte Chemie - International Edition 46 (31) : 5925-5928. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200701779|
|Abstract:||Trapped, then transformed: A discrete cyclic water heptamer with a twisted nonplanar conformation is trapped inside a 3D coordination polymeric crystal lattice with diamondoid topology. When a single crystal is cooled from 296 K to 223 K, it undergoes a phase transition accompanied by structural transformation of the cyclic water heptamer to a bicyclic structure (see scheme; Cu blue, O red, H white). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.|
|Source Title:||Angewandte Chemie - International Edition|
|Appears in Collections:||Staff Publications|
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