Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.200701779
Title: Phase transition accompanied by transformation of an elusive discrete cyclic water heptamer to a bicyclic (H2O)7 cluster
Authors: Mir, M.H.
Vittal, J.J. 
Keywords: Coordination polymers
Copper
Phase transitions
Self-assembly
Water clusters
Issue Date: 2007
Citation: Mir, M.H., Vittal, J.J. (2007). Phase transition accompanied by transformation of an elusive discrete cyclic water heptamer to a bicyclic (H2O)7 cluster. Angewandte Chemie - International Edition 46 (31) : 5925-5928. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200701779
Abstract: Trapped, then transformed: A discrete cyclic water heptamer with a twisted nonplanar conformation is trapped inside a 3D coordination polymeric crystal lattice with diamondoid topology. When a single crystal is cooled from 296 K to 223 K, it undergoes a phase transition accompanied by structural transformation of the cyclic water heptamer to a bicyclic structure (see scheme; Cu blue, O red, H white). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/94503
ISSN: 14337851
DOI: 10.1002/anie.200701779
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