Please use this identifier to cite or link to this item: https://doi.org/10.1021/ar050077y
Title: Pentamethylcyclopentadienyl ruthenium(III) vs hexamethylbenzene ruthenium(II) in sulfur-centered reactivity of their thioether-thiolate and allied complexes
Authors: Shin, R.Y.C.
Lai, Y.G. 
Issue Date: May-2006
Citation: Shin, R.Y.C., Lai, Y.G. (2006-05). Pentamethylcyclopentadienyl ruthenium(III) vs hexamethylbenzene ruthenium(II) in sulfur-centered reactivity of their thioether-thiolate and allied complexes. Accounts of Chemical Research 39 (5) : 301-313. ScholarBank@NUS Repository. https://doi.org/10.1021/ar050077y
Abstract: The reactivity features of [Cp*Ru III{η 3- tpdt)}] (7) and [(HMB)Ru II-(η 3-tpdt)] (10) {Cp* = η 5-C 5Me 5; HMB = η 6-C 6Me 6; tpdt = 3-thiapentane-1,5-dithiolate, S(CH 2CH 2S -) 2} are presented, together with selected aspects of their (η 3-apdt) analogues 8 and 11 {apdt = 3-azapentane-1,5-dithiolate, HN(CH 2CH 2S -) 2}. This account will highlight the differences observed in their reactions with metal fragments of compounds of Ru and groups 10 and 11 in various coordination environments and with alkylating agents, including α,ω-dibromoalkanes. The mechanistic pathway of the alkylation of 7 will be discussed in some detail. © 2006 American Chemical Society.
Source Title: Accounts of Chemical Research
URI: http://scholarbank.nus.edu.sg/handle/10635/94496
ISSN: 00014842
DOI: 10.1021/ar050077y
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