Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94489
Title: Pd(O2CCF2CF3-O)2(dppf) and PdAg(μ-O2CCF2CF3)2(O 2CCF2CF3-O)- (dppf)[dppf = 1,1′-bis(diphenylphosphino)ferrocene]: A stable Pd(II) phosphine carboxylate as a precursor to heterobimetallic carboxylates
Authors: Yew, C.N.
Vittal, J.J. 
Andy Hor, T.S. 
Issue Date: 2002
Source: Yew, C.N.,Vittal, J.J.,Andy Hor, T.S. (2002). Pd(O2CCF2CF3-O)2(dppf) and PdAg(μ-O2CCF2CF3)2(O 2CCF2CF3-O)- (dppf)[dppf = 1,1′-bis(diphenylphosphino)ferrocene]: A stable Pd(II) phosphine carboxylate as a precursor to heterobimetallic carboxylates. Journal of the Chemical Society, Dalton Transactions (3) : 337-342. ScholarBank@NUS Repository.
Abstract: Single crystal X-ray diffraction analysis of Pd(O2CCF2CF3-O)2(dppf) 1 shows that one of the two unidentate fluoropropanoates shows a rare bonding behavior with significant π character for the C = Ocoord bond whereas the C-Opendant bond is long and bears a basic function. Complex 1 serves as a metalloligand towards AgO2CCF2CF3 to give PdAg(μ-O2CCF2CF3)2(O 2CCF2CF3-O)(dppf) 2, which is fluxional in solution showing interchanges of the bridging and unidentatefluoropropanoate groups. Being an unusually stable Pd(II) carboxylate, 1 also serves an effective entry to mixed-metal carboxylates.
Source Title: Journal of the Chemical Society, Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/94489
ISSN: 1470479X
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

15
checked on Feb 17, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.