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|Title:||Palladium(II) and platinum(II) complexes with chelating sulfinyl functions|
|Authors:||Chooi, S.Y.M. |
|Source:||Chooi, S.Y.M.,Leung, P.-h.,Mok, K.F. (1993-03-15). Palladium(II) and platinum(II) complexes with chelating sulfinyl functions. Inorganica Chimica Acta 205 (2) : 245-247. ScholarBank@NUS Repository.|
|Abstract:||The synthesis of palladium and platinum complexes of (±)- Ph2ECH2CH2S(O)Me (EP, As) is described. A single crystal X-ray diffraction study of [(±)-Ph2PCH2CH2S(O)MePdCl2] reveals a square-planar geometry at the central atom which is attached by a chelate ring via the PS donors of the sulfinyl-substituted ligand. Similar structures are assigned to all four complexes by 1H NMR spectroscopy in d3-acetonitrile solutions. Oxygen-metal bonds are not involved in these molecules. © 1993.|
|Source Title:||Inorganica Chimica Acta|
|Appears in Collections:||Staff Publications|
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