Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0957-4166(97)00179-1
Title: Palladium(II) and platinum(II) complexes containing dimesyloxy-substituted chiral diamines
Authors: Lim, C.-C.
Mok, K.F. 
Sim, K.Y. 
Leung, P.-H. 
Issue Date: 27-Jun-1997
Citation: Lim, C.-C., Mok, K.F., Sim, K.Y., Leung, P.-H. (1997-06-27). Palladium(II) and platinum(II) complexes containing dimesyloxy-substituted chiral diamines. Tetrahedron Asymmetry 8 (12) : 2045-2050. ScholarBank@NUS Repository. https://doi.org/10.1016/S0957-4166(97)00179-1
Abstract: The physically stable but chemically reactive square-planar complex (+)-[(dichloro){S,S)-1,4-dimesyloxy-2,3-butanediamine}palladium(II)] and its platinum(II) analogue have been prepared from the reactions between the dihydrochloride salt of the diamine and K2MCl4 (where M = Pd, Pt) in water. The palladium complex has been analysed by X-ray crystallography. In contrast to their metal complexes, the free diamine ligand and its dihydrochloride salt are unstable and cannot be isolated.
Source Title: Tetrahedron Asymmetry
URI: http://scholarbank.nus.edu.sg/handle/10635/94473
ISSN: 09574166
DOI: 10.1016/S0957-4166(97)00179-1
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