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|Title:||Oligo- and polymeric PdII and PtII using pyridyl carboxylate spacers for topology control|
|Citation:||Teo, P., Koh, L.L., Hor, T.S.A. (2008-07-21). Oligo- and polymeric PdII and PtII using pyridyl carboxylate spacers for topology control. Inorganic Chemistry 47 (14) : 6464-6474. ScholarBank@NUS Repository. https://doi.org/10.1021/ic8007238|
|Abstract:||An array of PdII and PtII supramolecular assemblies have been constructed using pyridyl carboxylates as spacers and phosphines [(C5H4PPh2)2Fe (dppf) and PPh 3)] as supporting ligands. Different molecular topologies such as squares, triangles, rectangles, and polymers can be controlled by the spatial and directional character of the spacer. A change of the denticity of the phosphine does not affect the topological outcome. Significant differences, however, are observed for the congeneric analogues, with PdII showing a more pronounced tendency toward coordination polymer formation and its attached carboxyl a higher affinity toward Ag+. The ability of these assemblies to capture cations, such as Na+ in [Pt3Na(3- NC5H4CO2)3(OTf)3(PPh 3)6]+ through hydrogen bonding or Ag + in [PdAg(2-NC5H4CO2)(OTf) 2(dppf)] through dative bonding, is described and compared. All of the complexes are structurally characterized by single-crystal X-ray crystallography. © 2008 American Chemical Society.|
|Source Title:||Inorganic Chemistry|
|Appears in Collections:||Staff Publications|
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