Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/94413
DC Field | Value | |
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dc.title | o-diphenylphosphinobenzaldehyde complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structure | |
dc.contributor.author | Mahalakshmi, H. | |
dc.contributor.author | Phadnis, P.P. | |
dc.contributor.author | Jain, V.K. | |
dc.contributor.author | Tiekink, E.R.T. | |
dc.date.accessioned | 2014-10-16T08:35:44Z | |
dc.date.available | 2014-10-16T08:35:44Z | |
dc.date.issued | 2004-11 | |
dc.identifier.citation | Mahalakshmi, H.,Phadnis, P.P.,Jain, V.K.,Tiekink, E.R.T. (2004-11). o-diphenylphosphinobenzaldehyde complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structure. Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry 43 (11) : 2287-2293. ScholarBank@NUS Repository. | |
dc.identifier.issn | 03764710 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94413 | |
dc.description.abstract | Preparation of the o-diphenylphosphinobenzaldehyde complexes of Pd(II) and Pt(II), with general formulae [MX2L2], [Pd 2Me2(μ-Cl)2L2] and [PdMeClL 2] where [M = Pd or Pt; X = Cl, Br, I and L = o- diphenylphosphinobenzaldehyde, {PPh2(o-C6H 4CHO)}], is reported here. All complexes have been characterized by elemental analysis, IR, NMR (1H, 13C, 31P and 195Pt) and UV-visible spectroscopy, that allowed the deduction of the stereochemistry for the complexes. The mononuclear complexes have been found to adopt the trans configuration in square-planar geometries. The molecular structure of trans-[PdCl2{PPh2(C6H 4CHO)}2] has been established by a single crystal X-ray diffraction study and confirms the spectroscopic conclusions. | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry | |
dc.description.volume | 43 | |
dc.description.issue | 11 | |
dc.description.page | 2287-2293 | |
dc.description.coden | ICACE | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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