Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94413
Title: o-diphenylphosphinobenzaldehyde complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structure
Authors: Mahalakshmi, H.
Phadnis, P.P.
Jain, V.K.
Tiekink, E.R.T. 
Issue Date: Nov-2004
Source: Mahalakshmi, H.,Phadnis, P.P.,Jain, V.K.,Tiekink, E.R.T. (2004-11). o-diphenylphosphinobenzaldehyde complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structure. Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry 43 (11) : 2287-2293. ScholarBank@NUS Repository.
Abstract: Preparation of the o-diphenylphosphinobenzaldehyde complexes of Pd(II) and Pt(II), with general formulae [MX2L2], [Pd 2Me2(μ-Cl)2L2] and [PdMeClL 2] where [M = Pd or Pt; X = Cl, Br, I and L = o- diphenylphosphinobenzaldehyde, {PPh2(o-C6H 4CHO)}], is reported here. All complexes have been characterized by elemental analysis, IR, NMR (1H, 13C, 31P and 195Pt) and UV-visible spectroscopy, that allowed the deduction of the stereochemistry for the complexes. The mononuclear complexes have been found to adopt the trans configuration in square-planar geometries. The molecular structure of trans-[PdCl2{PPh2(C6H 4CHO)}2] has been established by a single crystal X-ray diffraction study and confirms the spectroscopic conclusions.
Source Title: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94413
ISSN: 03764710
Appears in Collections:Staff Publications

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