Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0022-328X(01)01419-X
Title: Observation of inter- and intramolecular C-H···F hydrogenbonding in Gingras' salt: [n-Bu4N]+ [Ph3SnF2]-
Authors: Beckmann, J.
Dakternieks, D.
Duthie, A.
Tiekink, E.R.T. 
Keywords: 119Sn MAS-NMR
Fluoride
Hypercoordination
Organotin
X-ray structures
Issue Date: 1-Apr-2002
Citation: Beckmann, J., Dakternieks, D., Duthie, A., Tiekink, E.R.T. (2002-04-01). Observation of inter- and intramolecular C-H···F hydrogenbonding in Gingras' salt: [n-Bu4N]+ [Ph3SnF2]-. Journal of Organometalic Chemistry 648 (1-2) : 204-208. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(01)01419-X
Abstract: The crystal and molecular structure of Gingras' salt [n-Bu 4N]+ [Ph3SnF2]- is reported, which reveals a variety of inter- and intramolecular C-H···F hydrogen bonding interactions. A 119Sn MAS-NMR spectrum was recorded and a tensor analysis has been performed according to the method of Herzfeld and Berger. The results are discussed in terms of the molecular structure and are compared with the parent compound Ph3SnF as well as with Mes3SnF (Mes = mesityl). © 2002 Elsevier Science B.V. All rights reserved.
Source Title: Journal of Organometalic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94410
ISSN: 0022328X
DOI: 10.1016/S0022-328X(01)01419-X
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