Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94374
Title: Novel condensation reactions of O-nitrosobis(trifluoromethyl)hydroxylamine and trifluoronitrosomethane with arsine
Authors: Ang, H.G. 
Lee, F.K.
Issue Date: Feb-1994
Source: Ang, H.G.,Lee, F.K. (1994-02). Novel condensation reactions of O-nitrosobis(trifluoromethyl)hydroxylamine and trifluoronitrosomethane with arsine. Journal of Fluorine Chemistry 66 (2) : 137-139. ScholarBank@NUS Repository.
Abstract: N-Bis(trifluoromethyl)nitroxy-iminoarsine, (CF3)2NONAsH, is formed by a condensation reaction betweenO- nitrosobis(trifluoromethyl)hydroxylamine and arsine. It undergoes reactions with (CF3)2NO to afford (CF3)2NONAsON(CF3)2 and bis(trifluoromethyl)hydroxylamine. Both the iminoarsines (CF3)2NONAsR (RH, (CF3)2NO) undergo addition reactions across the NAs bond with HI to give (CF3)2NONHAsIR. The reaction of trifluoronitrosomethane and arsine follows a similar pathway, affording an unstable iminoarsine, CF3NAsH, which decomposes via a free-radical mechanism even at low temperatures. © 1994.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94374
ISSN: 00221139
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

21
checked on Jan 20, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.