Please use this identifier to cite or link to this item:
|Title:||Mono-and dinuclear palladium(II) N,S-heterocyclic carbene complexes with N spacers and their Suzuki coupling activities|
|Authors:||Swee, K.Y. |
|Citation:||Swee, K.Y., Lip, L.K., Han, V.H., Hor, T.S.A. (2008-09-01). Mono-and dinuclear palladium(II) N,S-heterocyclic carbene complexes with N spacers and their Suzuki coupling activities. Chemistry - An Asian Journal 3 (8-9) : 1649-1656. ScholarBank@NUS Repository. https://doi.org/10.1002/asia.200800177|
|Abstract:||Mixed-ligand N,S-heterocyclic carbene (NSHC) complexes, trans-[PdBr 2(NSHC)(Py)] (NSHC=3-benzyl-or 3-propyl-benzothiazolin-2-ylidene), have been obtained from bridge-cleavage reactions of the dinuclear complex, [Pd(m-Br)Br(NSHC)]2, in pyridine at room temperature. Use of neutral N-bidentate donors (L=pyrazine, 1,2-bis(4-pyridyl)ethane, 4,4′-bipyridine and trans-1,2-bis(4-pyridyl)-ethylene) yields the dinuclear spacer-bridged [Pd2Br4(NSHC)2(μ-L)] complexes. The X-ray single-crystal structures of the pyridyl, bridging pyrazine and 1,2-bis(4-pyridyl)ethane complexes are reported. These air-stable complexes are active in the Suzuki-Miyaura coupling reactions of selected aryl bromides. The dinuclear complexes are generally more active than their mononuclear pyridyl analogues. The benzyl derivatives consistently outperform the n-propyl counterparts. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.|
|Source Title:||Chemistry - An Asian Journal|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
WEB OF SCIENCETM
checked on Sep 3, 2018
checked on Aug 3, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.