Please use this identifier to cite or link to this item:
|Title:||Mixed-ligand complex-formation of (2,2′,2″-terpyridine) copper(II) with monosubstituted phenolates|
|Authors:||Kwik, W.-L. |
|Citation:||Kwik, W.-L., Ang, K.-P. (1987-02). Mixed-ligand complex-formation of (2,2′,2″-terpyridine) copper(II) with monosubstituted phenolates. Transition Metal Chemistry 12 (1) : 58-62. ScholarBank@NUS Repository. https://doi.org/10.1007/BF01023134|
|Abstract:||The copper(II)-phenolate oxygen interaction in several mixed-ligand complexes of copper(II) containing a 2,2′,2″-terpyridyl and a phenolate has been studied by i.r., electronic, e.p.r. spectroscopies and conductometric and polarographic measurements. Electronic spectral results demonstrate the dependence of such interaction on the nature of the phenol as well as the solvent. Partial dissociation of the phenolate from the complex was detected in methanol at low concentrations (≤1×10-4M). In dimethyl sulphoxide the complexes remain intact. The X-band e.p.r. spectral data obtained at ambient temperature and at 77 K are consistent with the results from the electronic spectral and conductometric study. © 1987 Chapman and Hall Ltd.|
|Source Title:||Transition Metal Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Aug 17, 2018
WEB OF SCIENCETM
checked on Jul 3, 2018
checked on Jul 27, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.