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Title: Miscible blends of conductive polyaniline with tertiary amide polymers
Authors: Goh, S.H. 
Chan, H.S.O. 
Ong, C.H.
Keywords: Blends
Intermolecular interactions
Tertiary amide polymers
Issue Date: 13-Jun-1998
Citation: Goh, S.H.,Chan, H.S.O.,Ong, C.H. (1998-06-13). Miscible blends of conductive polyaniline with tertiary amide polymers. Journal of Applied Polymer Science 68 (11) : 1839-1844. ScholarBank@NUS Repository.
Abstract: Polyaniline (PANI) was doped with p -phenolsulfonic acid (PSA) or 5-sulfosalicylic acid (SSA). The PANI salts were blended with poly(N-vinyl-2-pyrrolidone), poly(N-methyl-N-vinylacetamide), poly(N,N-dimethylacrylamide), or poly(2-methyl-2-oxazoline) by solution casting from dimethyl sulfoxide. Blends containing up to 50% by weight of PANI salt were homogeneous and each exhibited a single glass transition temperature, indicating miscibility. Fourier transform infrared spectroscopic studies indicated that the carbonyl groups of the tertiary amide polymers interacted with the PANI salt as evidenced by the development of a shoulder at a lower frequency in the carbonyl stretching band. Electrical conductivities of the blends are in the range 10-5 to 10-3 S/cm, depending on the blend composition. © 1998 John Wiley & Sons, Inc.
Source Title: Journal of Applied Polymer Science
ISSN: 00218995
Appears in Collections:Staff Publications

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