Please use this identifier to cite or link to this item: https://doi.org/10.1021/om010649s
Title: Metal-metal bond opening toward main group-transition element rings
Authors: Leong, W.K. 
Chen, G.
Issue Date: 24-Dec-2001
Source: Leong, W.K., Chen, G. (2001-12-24). Metal-metal bond opening toward main group-transition element rings. Organometallics 20 (26) : 5771-5773. ScholarBank@NUS Repository. https://doi.org/10.1021/om010649s
Abstract: The reaction of the cluster Os6(μ4-Sb)(μ-H)2(μ-SbPh2) (μ3,η2-C6H4)(μ3 ,η4-C12H8)(CO)15, 1, with excess tBuNC resulted in ring expansion via metal-metal bond cleavage to afford the novel compounds Os6(μ4-Sb)(μ-H)(μ-SbPh2)(C6 H5) (μ3,η4-C12H8) (CO)14(CNtBu)4, 2, and Os6-(μ4-Sb)(μ-H)(μ-SbPh2) (C6H5) (μ3,η4-C12H8) (CO)15(CNt-Bu)3, 3, both of which contain five-membered Os3Sb2 rings.
Source Title: Organometallics
URI: http://scholarbank.nus.edu.sg/handle/10635/94215
ISSN: 02767333
DOI: 10.1021/om010649s
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