Please use this identifier to cite or link to this item: https://doi.org/10.1021/ar600003h
Title: Metal unsaturation and ligand hemilability in Suzuki coupling
Authors: Weng, Z. 
Teo, S.
Hor, T.S.A. 
Issue Date: Aug-2007
Citation: Weng, Z., Teo, S., Hor, T.S.A. (2007-08). Metal unsaturation and ligand hemilability in Suzuki coupling. Accounts of Chemical Research 40 (8) : 676-684. ScholarBank@NUS Repository. https://doi.org/10.1021/ar600003h
Abstract: The combinative and complementary use of a hemilabile difunctional ligand on a metal, notably palladium, that is coordinatively and electronically unsaturated has led to the isolation of a string of unexpected low-valent complexes that are structurally intriguing. The ligands of interest are primarily ferrocenes functionalized by [P,N] and [P,O] donors. The characterization of these active Suzuki catalysts, which support sp 2-sp2 couplings, give valuable insights into the key Suzuki intermediates such as those arising from the reductive elimination, transmetallation, and oxidative addition steps. In this Account, we shall review and discuss our recent results in relation to selected developments in other laboratories. © 2007 American Chemical Society.
Source Title: Accounts of Chemical Research
URI: http://scholarbank.nus.edu.sg/handle/10635/94211
ISSN: 00014842
DOI: 10.1021/ar600003h
Appears in Collections:Staff Publications

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