Please use this identifier to cite or link to this item: https://doi.org/10.1021/ic010905t
Title: Metal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod)
Authors: Yeo, J.S.L. 
Vittal, J.J. 
Henderson, W.
Hor, T.S.A. 
Issue Date: 11-Mar-2002
Citation: Yeo, J.S.L., Vittal, J.J., Henderson, W., Hor, T.S.A. (2002-03-11). Metal scrambling in the trinuclear Pt-Se-M (M=Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of two Pt-Se-Pt hexafluorophosphine complexes (see abstract) with the cycloocta-1,5-diene ligand (cod). Inorganic Chemistry 41 (5) : 1194-1198. ScholarBank@NUS Repository. https://doi.org/10.1021/ic010905t
Abstract: Pt2(μ-Se)2(PPh3)4 reacts with PtCl2(cod) to give {Pt2(μ3-Se)2(PPh3) 4[Pt(cod)]}2+ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ3-Se)2(PPh3)2[Pt(cod)] 2}2+. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.
Source Title: Inorganic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94210
ISSN: 00201669
DOI: 10.1021/ic010905t
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