Please use this identifier to cite or link to this item: https://doi.org/10.1039/c3dt52176a
Title: Magnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates
Authors: Wang, P.
Shannigrahi, S.
Yakovlev, N.L.
Hor, T.S.A. 
Issue Date: 7-Jan-2014
Citation: Wang, P., Shannigrahi, S., Yakovlev, N.L., Hor, T.S.A. (2014-01-07). Magnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates. Dalton Transactions 43 (1) : 182-187. ScholarBank@NUS Repository. https://doi.org/10.1039/c3dt52176a
Abstract: A new series of remarkably isostructural 3d-4f compounds, [Ni 3Ln(hmp)4(OAc)5]·H2O· CH2Cl2 (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Y (5)) were synthesized based on a simple one-pot self-assembly method. Magnetic measurements demonstrated the ferromagnetic property of the [Ni3Ln] cores and the heterometallic influence on the magnetocaloric properties. This study suggested that robust and discrete intermetallic cubanes can be an alternative to other magnetically active materials such as high-nuclearity aggregates or clusters whose structures are not generally controlled by common synthetic methodological designs. © 2014 The Royal Society of Chemistry.
Source Title: Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/94181
ISSN: 14779226
DOI: 10.1039/c3dt52176a
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

10
checked on Sep 17, 2018

WEB OF SCIENCETM
Citations

7
checked on Sep 17, 2018

Page view(s)

41
checked on Jun 29, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.