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https://doi.org/10.1039/b802043d
Title: | Isolation of an [SNS]Pd(II) pincer with a water ladder and its Suzuki coupling activity in water | Authors: | Bai, S.-Q. Hor, T.S.A. |
Issue Date: | 2008 | Citation: | Bai, S.-Q., Hor, T.S.A. (2008). Isolation of an [SNS]Pd(II) pincer with a water ladder and its Suzuki coupling activity in water. Chemical Communications (27) : 3172-3174. ScholarBank@NUS Repository. https://doi.org/10.1039/b802043d | Abstract: | A water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L 1PdCl]Cl·2H2O [L1 = bis-(2-(i- butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki-Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75°C. © The Royal Society of Chemistry. | Source Title: | Chemical Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/94116 | ISSN: | 13597345 | DOI: | 10.1039/b802043d |
Appears in Collections: | Staff Publications |
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