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|Title:||Isolation and structural characterisation of a reactive chiral palladium(II) complex containing a ClO4 ligand|
|Citation:||Loh, S.-K., Mok, K.F., Leung, P.-H., White, A.J.P., Williams, D.J. (1996). Isolation and structural characterisation of a reactive chiral palladium(II) complex containing a ClO4 ligand. Tetrahedron Asymmetry 7 (1) : 45-48. ScholarBank@NUS Repository. https://doi.org/10.1016/0957-4166(95)00417-3|
|Abstract:||The organopalladium(II) complex [Pd(OClO3)(DMPP)→(S)-CH3CH(1-C10H6)NMe2←] (where DMPP = 1-phenyl-3,4-dimethylphosphole) has been isolated. X-ray structural analysis of this reactive complex in the solid state revealed that the perchlorato ligand is bonded to Pd via one of its oxygen atoms and the DMPP is coordinated as a mondentate ligand via phosphorus. In noncoordinating solvents, conductivity measurements confirmed that the Pd-OClO3 bond is retained.|
|Source Title:||Tetrahedron Asymmetry|
|Appears in Collections:||Staff Publications|
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