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Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2007.11.031
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dc.titleIsolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)
dc.contributor.authorNeo, K.E.
dc.contributor.authorHuynh, H.V.
dc.contributor.authorKoh, L.L.
dc.contributor.authorHenderson, W.
dc.contributor.authorHor, T.S.A.
dc.date.accessioned2014-10-16T08:32:15Z
dc.date.available2014-10-16T08:32:15Z
dc.date.issued2008-04-15
dc.identifier.citationNeo, K.E., Huynh, H.V., Koh, L.L., Henderson, W., Hor, T.S.A. (2008-04-15). Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II). Journal of Organometallic Chemistry 693 (8-9) : 1628-1635. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2007.11.031
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/94111
dc.description.abstractPincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. © 2007 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2007.11.031
dc.sourceScopus
dc.subjectPalladium
dc.subjectPhosphine
dc.subjectPincer
dc.subjectSuzuki-Miyaura Coupling
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2007.11.031
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume693
dc.description.issue8-9
dc.description.page1628-1635
dc.description.codenJORCA
dc.identifier.isiut000255891400030
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