Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2007.11.031
Title: Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)
Authors: Neo, K.E.
Huynh, H.V. 
Koh, L.L. 
Henderson, W.
Hor, T.S.A. 
Keywords: Palladium
Phosphine
Pincer
Suzuki-Miyaura Coupling
Issue Date: 15-Apr-2008
Citation: Neo, K.E., Huynh, H.V., Koh, L.L., Henderson, W., Hor, T.S.A. (2008-04-15). Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II). Journal of Organometallic Chemistry 693 (8-9) : 1628-1635. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2007.11.031
Abstract: Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. © 2007 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94111
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2007.11.031
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