Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2013.05.021
Title: Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium
Authors: Ning Wong, K.
Mak, K.H.G.
Fan, W.Y. 
Sridevi, V.S.
Leong, W.K.
Keywords: CeC coupling
Conjugated carbonyl
Iridafuran
Iridium
Terminal alkyne
Issue Date: 2013
Source: Ning Wong, K., Mak, K.H.G., Fan, W.Y., Sridevi, V.S., Leong, W.K. (2013). Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium. Journal of Organometallic Chemistry 741-742 (1) : 40-46. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2013.05.021
Abstract: Reaction of the dimeric species [Cp IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in CeC bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.© 2013 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94107
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2013.05.021
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