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|Title:||Investigations on the solid state interaction between LiAlH4 and NaNH2|
|Citation:||Chua, Y.S., Wu, G., Xiong, Z., Chen, P. (2010-09). Investigations on the solid state interaction between LiAlH4 and NaNH2. Journal of Solid State Chemistry 183 (9) : 2040-2044. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jssc.2010.07.014|
|Abstract:||In this paper, two LiAlH4NaNH2 samples with LiAlH4 to NaNH2 molar ratio of 1/2 and 2/1 were investigated, respectively. It was observed that both samples evolved 2 equiv H2 in the ball milling process, however, the reaction pathways were different. For the LiAlH4NaNH2 (1/2) sample, Li 3Na(NH2)4 and NaAlH4 were formed through cation exchange between reactants. The NaAlH4 formed further reacts with Li3Na(NH2)4 and NaNH2 to give H2, NaH and LiAlN2H2. For the LiAlH 4NaNH2 (2/1) sample, Li3Na(NH2) 4, LiNH2 and NaAlH4 were formed firstly through the same cation exchange process. The resulting LiNH2 reacts with the remaining LiAlH4 and produces H2 and Li 2AlNH2. © 2010 Elsevier Inc. All rights reserved.|
|Source Title:||Journal of Solid State Chemistry|
|Appears in Collections:||Staff Publications|
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