Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2004.11.009
Title: Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 2(μ3-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)2(μ3-S)2] · 2CH2Cl2
Authors: Li, G.
Lam, C.-K.
Chien, S.W. 
Mak, T.C.W.
Andy Hor, T.S. 
Keywords: Ferrocenyl
Heterometallic
Metalloligand
Palladium
Phosphine
Structure
Sulfide
Issue Date: 14-Feb-2005
Source: Li, G., Lam, C.-K., Chien, S.W., Mak, T.C.W., Andy Hor, T.S. (2005-02-14). Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 2(μ3-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)2(μ3-S)2] · 2CH2Cl2. Journal of Organometallic Chemistry 690 (4) : 990-997. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2004.11.009
Abstract: Lewis acid/base addition between Pd2(dppf)2(μ-S) 2 and MXn [M = In(III), Ga(III), Tl(I), Pb(II), Sn(IV), Bi(III), Ag(I) and Au(I); X = halide or pseudohalide; dppf = 1,1′-bis(diphenylphosphino)ferrocene] gives rise to a range of neutral or cationic intermetallics aggregates with the {Pd2MS2} or {Pd2M2S2} core. Effectively Pd 2(dppf)2(μ-S)2 functions as a chelating or bridging dithio metalloligand. Two representative crystal structures, viz. [InPd2Cl3(dppf)2(μ3-S) 2] · 3CH2Cl2 and [Ag2Pd 2(NO3)2(dppf)2(μ3-S) 2] · 2CH2Cl2 are described and discussed. The former features an intermetallic {InPd2} triangle whereas the latter displays a heterometallic {Ag2Pd2} metal plane. Both of them are sustained and supported by capping sulfides without significant or direct metal-metal bonds. © 2004 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94059
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2004.11.009
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