Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/93957
Title: High-performance liquid chromatography of Group 6 dimetal decacarbonyl complexes singly-bridged by diphosphine ligands
Authors: Tan, K.-C.
Hor, T.S.A. 
Lee, H.K. 
Issue Date: Oct-1994
Source: Tan, K.-C.,Hor, T.S.A.,Lee, H.K. (1994-10). High-performance liquid chromatography of Group 6 dimetal decacarbonyl complexes singly-bridged by diphosphine ligands. Journal of Liquid Chromatography 17 (17) : 3671-3680. ScholarBank@NUS Repository.
Abstract: The normal-phase high-performance liquid chromatography of a series of Group 6 dimetal decacarbonyl complexes, of the form (OC)5M(P(CH2)(n)P)M(CO)5, where M = Cr, Mo and W, and P(CH2)(n)P = diphenylphosphinyl bridge with n = 2-6, is reported. Chromatography was carried out on a stainless steel column packed with silica to which polar amino-cyano groups have been bonded; hexane-chloroform was used as mobile phase. The retention behaviour of these homometallic complexes is discussed.
Source Title: Journal of Liquid Chromatography
URI: http://scholarbank.nus.edu.sg/handle/10635/93957
ISSN: 01483919
Appears in Collections:Staff Publications

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