Please use this identifier to cite or link to this item:
|Title:||Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand|
|Citation:||Ng, S.Y., Goh, L.Y., Koh, L.L., Leong, W.K., Tan, G.K., Ye, S., Zhu, Y. (2006-02-06). Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand. European Journal of Inorganic Chemistry (3) : 663-670. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.200500785|
|Abstract:||The salt elimination reaction between NaCo(CO)4 and the ruthenium complexes LRu(diphos)Cl and [(Ind)Ru(CO)2Cl] afforded the Ru-Co bimetallic complexes [LRu(μ-CO)2(μ-diphos)Co(CO) 2] [L = C5Me5 (Cp*), diphos = Ph 2P(CH2)nPPh2, 3a: n = 1 , or 3b: n = 2; 3. L = C9H7 (Ind), diphos = Ph2PCH 2PPh2 ] and [(Ind)Ru(CO)2Co(CO)4] (3d), respectively, in high yields. However, the same reaction with the monophosphane analogue, [(Ind)Ru(PPh3)2Cl], gave the heterobimetallic complex [(Ind)Ru(PPh3)(CO)(μ-CO)Co(CO) 3] (3e) in fair yield, together with redox-initiated derivatives Ru(PPh3)2(CO)3 (4e) and [(Ind)Co(CO)(PPh 3)] (6e). A similar redox process in the reaction of the dppf analogue, [(Ind) Ru(dppf)Cl] (dppf = 1,1′-diphenylphosphanylferrocene) gave [Ru(dppf)(CO)3] (4f) and [(Ind)Co(CO)2] (6f), together with a complex salt [(Ind)Ru(dppf)(CO)][Co(CO4)] [5f·Co(CO)4]. © Wiley-VCH Verlag GmbH & Co. KGaA, 2006).|
|Source Title:||European Journal of Inorganic Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jul 13, 2018
WEB OF SCIENCETM
checked on Jun 12, 2018
checked on Jun 29, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.