Please use this identifier to cite or link to this item:
|Title:||Gold(III) thiosalicylate complexes containing cycloaurated 2-arylpyridine, 2-anilinopyridine and 2-benzylpyridine ligands|
|Citation:||Henderson, W., Nicholson, B.K., Faville, S.J., Fan, D., Ranford, J.D. (2001-08-10). Gold(III) thiosalicylate complexes containing cycloaurated 2-arylpyridine, 2-anilinopyridine and 2-benzylpyridine ligands. Journal of Organometallic Chemistry 631 (1-2) : 41-46. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(01)00987-1|
|Abstract:||Reactions of the gold(III) dichloride complexes [(N_C)AuCl2] ((N_C)=cycloaurated 2-phenylpyridine, 2-(p-tolyl)pyridine, 2-anilinopyridine or 2-benzylpyridine) with thiosalicylic acid (2-mercaptobenzoic acid, HSC6H4CO2H) and base gives a series of gold(III) thiosalicylate complexes [(N_C)Au(SC6H4CO2)]. A crystal structure determination on the 2-p-tolylpyridine derivative is reported, confirming the presence of a chelating thiosalicylate ligand, with the tolyl and thiolate groups mutually cis, together with a highly puckered gold-thiosalicylate moiety, and a twisted carboxylate group. The activity of the thiosalicylate complexes against P388 leukaemia cells has been determined. © 2001 Elsevier Science B.V.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Oct 16, 2018
WEB OF SCIENCETM
checked on Oct 8, 2018
checked on Oct 19, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.